
TY  - JOUR
A1  - Kooner, ZS 
A1  - Fenby, DV 
T1  - Thermodynamics of deuterium exchange reactions in water-amine and alcohol-amine systems
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 9
SP  - 1801
EP  - 1807
KW  - 
UR  - https://doi.org/10.1071/CH9811801 
N2  - Vapour pressures and molar excess enthalpies at 298.15 K are reported for the systems H2O+(C2H5)2NH and D2O+(C2H5)2NH. They are analysed to give the equilibrium constant and enthalpy of the reaction                   2(C2H5)2NH(1)+D2O(1)&#8594;2(C2H5)2ND(1)+H2O(1) Molar excess enthalpies at 298.15 K of the systems CH3OH+(C2H5)2NH, CH3OD+(C2H5)2NH, C2H5OH+(C2H5)2NH and C2H5OD+(C2H5)2NH are used to obtain enthalpies of the reactions            (C2H5)2NH(1)+ROD(1)&#8594;(C2H5)2ND(1)+ROH(1)  (R = CH3, C2H5)Thermodynamic properties of various NH/OD exchange reactions are calculated from statistical mechanical equations by use of harmonic frequencies. 
ER  -

