
TY  - JOUR
A1  - Arthur, NL 
A1  - David, LF 
T1  - Reactions of trifluoromethyl radicals. VI. Hydrogen abstraction from trifluoroacetic acid and trifluoroacetic (<sup>2</sup>H<sub>1</sub>)acid
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 7
SP  - 1535
EP  - 1538
KW  - 
UR  - https://doi.org/10.1071/CH9811535 
N2  - The hydrogen abstraction reactions of CF3 radicals with CF3COOH and CF3COOD CF3 + CF3COOH &#8594; CF3H + CF3COO                 (1)CF3 + CF3COOD &#8594; CF3D + CF3COO                 (2) have been studied in the temperature ranges 102-225&#176;C and 153-275&#176;C respectively. The rate constants, based on the value of 1013.36 cm3 mol-1 s-1 for the recombination of CF3 radicals, are given by (k in cm3 mol-1 s-1 and E in J mol-1):  logk1 = (10.17±0.12)-(33140±970)/19.145T                      logk2 = (9.51±0.11)-(46090±1010)/19.145T 
ER  -

