
TY  - JOUR
A1  - Bloom, H 
A1  - White, MS 
T1  - Thermodynamic properties of the binary molten salt systems, PbBr<sub>2</sub>-KBr, PbBr<sub>2</sub>-RbBr and PbBr<sub>2</sub>-CsBr, by measurement of the electromotive forces of galvanic cells
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 3
SP  - 479
EP  - 487
KW  - 
UR  - https://doi.org/10.1071/CH9810479 
N2  - The electromotive forces of galvanic cells for the formation of PbBr2 in the molten binary salt systems, PbBr2-KBr, PbBr2,-RbBr and PbBr2-CsBr, have been measured. Activities, activity coefficients and partial molar free energies have been calculated for each component of the three systems. Integral free energies of mixing have also been calculated. Various models of mixing of molten salts have been applied to the results. The systems contain complex ions, probably mixtures of PbBr42-, PbBr64- with some PbBr3-. 
ER  -

