
TY  - JOUR
A1  - Collins, DJ 
A1  - Jackson, WR 
A1  - Timms, RN 
T1  - The stereochemistry of proton removal in the formation of &#960;-allyl palladium complexes from steroid 4-En-3-ones
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 12
SP  - 2663
EP  - 2672
KW  - 
UR  - https://doi.org/10.1071/CH9802663 
N2  - Reaction of (6&#946;-2H)- and (6&#945;-2H)-cholest-4-en-3-one with palladium(II) chloride in dry tetrahydro- furan gives the &#945;-4-6-&#951;-PdCl compound with highly stereoselective loss of the 6&#946; deuterium or proton. The mechanistic implications of this stereoselectivity are discussed. 
ER  -

