
%0 Journal Article
%A Collins, DJ 
%A Jackson, WR 
%A Timms, RN 
%T The stereochemistry of proton removal in the formation of &#960;-allyl palladium complexes from steroid 4-En-3-ones
%J Australian Journal of Chemistry
%D 1980/12/01
%V 33
%N 12
%P 2663-2672
%K 
%R https://doi.org/10.1071/CH9802663
%U https://www.publish.csiro.au/paper/CH9802663 
%X Reaction of (6&#946;-2H)- and (6&#945;-2H)-cholest-4-en-3-one with palladium(II) chloride in dry tetrahydro- furan gives the &#945;-4-6-&#951;-PdCl compound with highly stereoselective loss of the 6&#946; deuterium or proton. The mechanistic implications of this stereoselectivity are discussed. 
