
TY  - JOUR
A1  - Guthrie, RD 
A1  - Jenkins, ID 
A1  - Watters, JJ 
T1  - 1'-Derivatives of sucrose and their acid hydrolysis
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 11
SP  - 2487
EP  - 2497
KW  - 
UR  - https://doi.org/10.1071/CH9802487 
N2  - Syntheses of 1'-chloro-1'-deoxy- and 1'-deoxy-sucrose are described. Several routes were investigated, the most successful being through 6,1',6'-tri-O-(2,4,6-trimethylbenzenesulfonyl)sucrose. Attempts to prepare 1'-deoxy-1'-fluorosucrose were unsuccessful. The rates of the acid-catalysed hydrolysis of 1'-chloro-1'-deoxysucrose and of 1'- deoxysucrose have been measured. These values are compared with that for sucrose itself. The mechanism of the hydrolyses is discussed. 
ER  -

