
TY  - JOUR
A1  - Jackson, WR 
A1  - Nicolson, DM 
T1  - Reactions over supported metal catalysts. VI. The effect of halogen compounds on transition metal catalysts supported on silica or pumice. Reactions of 3-methylnortricyclene
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 10
SP  - 2261
EP  - 2269
KW  - 
UR  - https://doi.org/10.1071/CH9802261 
N2  - The product distributions from reactions of 3-methylnortricyclene with hydrogen over palladium or platinum catalysts supported on silica or pumice vary significantly after treatment of the catalyst with small amounts of halogen-containing compounds. Evidence is presented, including deuterium distribution studies utilizing 2H N.M.R., that these changes in products are associated with intermediates which have greater sp2 character at the reacting carbon atoms and that the formation of intermediates is not simply associated with an increase in catalyst acidity. 
ER  -

