
TY  - JOUR
A1  - Steenkamp, PJ 
A1  - Gonsalves, JW 
T1  - Symmetry-based equivalence between the crystal-field and angular-overlap models
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 8
SP  - 1705
EP  - 1711
KW  - 
UR  - https://doi.org/10.1071/CH9801705 
N2  - Ratios between the cubic ligand-field parameters &#916;, as predicted by the crystal-field model, are presented and compared with those obtained when utilizing the angular-overlap model. The remarkable similarities revealed are attributed to symmetry by introducing a symmetry- orientated reparameterization of the crystal-field model. A new parametric equivalence between the two models, based on the effects of symmetry, is established. Arguments suggesting a unified model are outlined. 
ER  -

