
%0 Journal Article
%A Long, MA 
%A Garnett, JL 
%A Lukey, CA 
%A Williams, PG 
%T Metal-catalysed exchange of alkyl and silyl hydrogen in organosilanes with tritium gas over Raney nickel as measured by <sup>3</sup>H N.M.R
%J Australian Journal of Chemistry
%D 1980/06/01
%V 33
%N 6
%P 1393-1395
%K 
%R https://doi.org/10.1071/CH9801393
%U https://www.publish.csiro.au/paper/CH9801393 
%X Analysis by tritium n.m.r, of triethylsilane, tetramethylsilane, hexamethyldisiloxane and chlorodimethylsilane exchanged with tritium gas over Raney nickel at 100&#176;C shows that exchange readily occurs in alkyl substituents as well as with silyl hydrogen; novel species involving charge-transfer intermediates in dissociative adsorption at the C-H as well as the Si-H bonds are proposed to explain the data. 
