
TY  - JOUR
A1  - Coates, JH 
A1  - Collins, PR 
A1  - Lincoln, SF 
T1  - Ligand substitution at five-coordinate copper(II) centres by cyanate, chloride and bromide ions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 6
SP  - 1381
EP  - 1387
KW  - 
UR  - https://doi.org/10.1071/CH9801381 
N2  - The substitution of the aqua[tris{2-(dimethylamino)ethyl}amine]copper(II) ion by cyanate, chloride and bromide ions has been studied in aqueous solution by static and stopped-flow spectrophoto-metric techniques. This process is unusually slow for ligand substitution at a copper(II) centre and appears to proceed through an interchange mechanism in which the copper(II)-aqua ligand bond makes a major contribution to the transition state energetics. 
ER  -

