
TY  - JOUR
A1  - Koner, ZS 
A1  - Phutela, RC 
A1  - Fenby, DV 
T1  - Determination of the equilibrium constants of water-methanol deuterium exchange reactions from vapour pressure measurements
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 1
SP  - 9
EP  - 13
KW  - 
UR  - https://doi.org/10.1071/CH9800009 
N2  - The equilibrium constant of the reaction2CH3OH(l) + D2O(l) &#8594; 2CH3OD(l) + H2O(l) is obtained from vapour pressure measurements. The value, 1.09k0.02 at 298 K, is in satisfactory agreement with calculated values and with calorimetric estimates. Vapour pressures at 298.14 K are reported for the systems H2O + CH3OH, H2O+CH3OD, D2O + CH3OH and D2O+ CH3OD. Molar excess Gibbs functions are obtained from these vapour pressures. 
ER  -

