
TY  - JOUR
A1  - Arthur, NL 
A1  - Yeo, KS 
T1  - Hydrogen Abstraction from Dimethyl Sulfide by Trifluoromethyl Radicals
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 9
SP  - 2077
EP  - 2078
KW  - 
UR  - https://doi.org/10.1071/CH9792077 
N2  - Additional data are presented for hydrogen abstraction from (CH3)2,S by CF3 radicals         CF3+(CH3)2S &#8594; CF3H+CH2SCH2 (1) leading to a revised value for the rate constant (k in cm3 mol-1 s-1, E in J mol-1):      logk1 = (11·83±0·06)-(26910±450)/19.16T Combination of these results with thermochemical data gives a revised value of      logk-1 = 11·9-61800/19·145Tfor the rate constant of the reverse reaction. 
ER  -

