
%0 Journal Article
%A Pasaribu, SJ 
%T Encephalitogenic Peptides: Synthesis and <sup>13</sup>C N.M.R. of a Pentapeptide Fragment of Myelin Basic Protein of the (65-74) Region
%J Australian Journal of Chemistry
%D 1979/07/01
%V 32
%N 7
%P 1575-1583
%K 
%R https://doi.org/10.1071/CH9791575
%U https://www.publish.csiro.au/paper/CH9791575 
%X The synthesis, by stepwise conventional method, of a fully protected pentapeptide, Boc-Ser(OBzl)- Leu-Pro-Gln-Lys(N8-Cbz)-OBzl, a fragment of the MBP 65-74 region, is described. 13C N.M.R. of the intermediates are discussed, and it was observed that proline gave rise only to the trans- conformation. The benzyl ether protecting group of the serine side chain was found to cause the &#946;-carbon to resonate at a lower field, whereas the &#945;-carbon experienced an upfield shift. 
