
TY  - JOUR
A1  - Abu, Salah OM 
A1  - Bruce, MI 
A1  - Walsh, JD 
T1  - Chemistry of the Group 1B Metals. XI. Further Studies of Some Poly(pyrazolyl)-borate Complexes of Copper(I)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 6
SP  - 1209
EP  - 1218
KW  - 
UR  - https://doi.org/10.1071/CH9791209 
N2  - A series of 21 poly(pyrazolyl)borate complexes of copper(I) have been prepared either (i) from reactions between the appropriate carbonyl derivatives, Cu(CO)[(pz)3BR](R = H or pz) or Cu(CO)[(Me2pz)3-BH], and donor ligands, L, or (ii) from reactions between copper(I) chloride, L, and the appropriate poly(pyrazolyl)borate anion [H2B(pz)2-,ph2B(pz)3-, HB(pz)3-, HB(Me2pz)3- or B(pz)4-]. Complexes containing L = CO, PEt3, P(C6H4Me)3 (C6H4Me = o-, m- or p-tolyl), As(C6H4Me-p)3,P(OMe)3, P(OMe)3 (OPh)3, dppm, dppe, diars, MeC(CH2PPh2)3 or ButNC are described. Most contain four-coordinate copper(I), although the bis(pyrazolyl)borate complexes are formally three-coordinate. 
ER  -

