
TY  - JOUR
A1  - Arthur, NL 
A1  - Christie, JR 
A1  - Mitchell, GD 
T1  - Reactions of Trifluoromethyl Radicals. IV. Hydrogen Abstraction from Dichlorosilane and Trichlorosilane
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 5
SP  - 1017
EP  - 1023
KW  - 
UR  - https://doi.org/10.1071/CH9791017 
N2  - The hydrogen abstraction reactions of SiH2Cl2 and SiHCl2 with CF3 radicals  CF3+SiH2Cl2 &#8594; CF3H + SiHCl2 CF3+SiH2Cl3 &#8594; CF3H + SiHCl3 have been studied in the temperature ranges 65-227ºand 64-294º, respectively. The rate constants, based on the value of 1013.36 cm3 mol-1 s-1 for the recombination of CF3 radicals, are given by (k in cm3 mol-1 s-1, E in J mol-1): logk1 = (12.08 ± 0.04)-(25600 ± 280)/19.145T logk2 = (11.92 ± 0.02)-(27020 ± 160)/19.145T 
ER  -

