
TY  - JOUR
A1  - Bottomley, GA 
A1  - Glossop, LG 
A1  - Staunton, WP 
T1  - Dilatometer Studies of the Apparent Molar Volume Limiting Law for High-Charge Electrolytes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 4
SP  - 699
EP  - 708
KW  - 
UR  - https://doi.org/10.1071/CH9790699 
N2  - A continuous-dilution dilatometer, of the tilting type, specifically designed for study of the apparent molar volumes of aqueous electrolytes at low concentrations, is described. Results at 298.16 K have been secured for multivalent (± 3, ± 4, ± 6) univalent electrolytes which demonstrate that the apparent molar volumes vary with c½ in approximate conformity with the Debye-Huckel limiting-law slopes. Data are presented for: [Co(en)3] Cl3, K3 [CO(CN)6], [Pt(en)3] Cl4, K4 [Mo(CN)8], [C0{(0H)2Co(en)2}3] (NO3)6,Na6C6(C00)6, K4 [Fe(CN)6] and [Co(en)3] (C1O4)3 Ion pairing is a significant disturbing factor which hinders treatment of the data in terms of extended forms of the Debye-Huckel equation. 
ER  -

