
TY  - JOUR
A1  - Skelton, BW 
A1  - White, AH 
T1  - Crystal Structure of Sodium O,O'-Nitritonitroargentate(I)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 2
SP  - 297
EP  - 300
KW  - 
UR  - https://doi.org/10.1071/CH9790297 
N2  - The crystal structure of the title compound, NaAg(NO2)2, has been determined by single-crystal X-ray diffraction at 295(1) K and refined by full-matrix least squares to a residual of 0.043 for 449 'observed' reflections. Crystals are orthorhombic, space group Fd2d, a 7.913(2), b 10.721(2), c 10.857(3) Å, Z 8. The structure is closely related to that of sodium and silver nitrites; the silver environment is dominated by the 'linear' coordination of a nitro group (Ag-N 2.25(2) Å) and a 'chelating' pair of oxygen atoms from another NO2- species (Ag-O 2.422(8)Å), the O2N-Ag-O2N group containing a crystallographic 2 axis. 
ER  -

