
%0 Journal Article
%A Raston, CL 
%A White, AH 
%A Yandell, JK 
%T Crystal Structure of Disodium(I) <I>cis</I>-Bis(ethane-1,2-diamine)disulfitocobaltate(III) Perchlorate Trihydrate
%J Australian Journal of Chemistry
%D 1979/02/01
%V 32
%N 2
%P 291-296
%K 
%R https://doi.org/10.1071/CH9790291
%U https://www.publish.csiro.au/paper/CH9790291 
%X The crystal structure of the title compound, Na2C104 [CO(C2N2H8)2(SO3)2],3H2O, has been determined by single-crystal X-ray diffraction at 295(1) K and refined by least squares to a residual of 0.033 for 2693 'observed' reflections. Crystals are monoclinic, P21/c, a 16.271(3), b 12.298(2), c 9.567(2) Å, &#946; 105.85(1)º, Z 4. The Co-S distances differ significantly, probably a consequence of interaction of the sulfite oxygen atoms with adjacent sodium ions [Co-S, 2.206(1), 2.233(1) Å]; the Co-N distances trans to the sulfite groups are significantly longer [2.015(3), 2.003(4) Å] than those trans to each other [1.964(4), 1.959(3) Å]. 
