
TY  - JOUR
A1  - Black, DSC 
A1  - Doyle, JE 
T1  - Nitrones and oxaziridines. XXII. Preparation and cyclization of some &#948;,&#949;-unsaturated hydroxylamines
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 10
SP  - 2317
EP  - 2322
KW  - 
UR  - https://doi.org/10.1071/CH9782317 
N2  - Four &#948;,&#949;-unsaturated hydroxylamines have been prepared by reduction of the related oximes by sodium cyanoborohydride. Only two of these-those containing terminal olefinic groups-undergo spontaneous cyclization to N-hydroxypyrrolidines, which can be oxidized easily to 1-pyrroline 1-oxides. The acyclic and cyclic hydroxylamines have been characterized by their products of reaction with phenyl isocyanate. 
ER  -

