
TY  - JOUR
A1  - Cannon, JR 
A1  - Patrick, VA 
A1  - White, AH 
T1  - The crystal structure of 1&#945;,4a&#946;,6&#946;,9a&#945;-Tetrahydroxy-4a,5a&#945;,9a,10a&#946;-tetrahydrodibenzo[b,e][1,4]dioxin-2,7(1H,6H)-dione&#8211; A dimeric oxidation product of quinol
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 10
SP  - 2213
EP  - 2218
KW  - 
UR  - https://doi.org/10.1071/CH9782213 
N2  - A single-crystal structure determination has revealed that the product obtained by oxidation of quinol with sodium chlorate and osmium tetroxide and crystallized from dimethyl sulfoxide is a solvate of 1&#945;,4a&#946;,6&#946;,9a&#945;-tetrahydroxy-4a,5a&#945;,9a,10a&#946;-tetrahydrodibenzo[b,e][1,4]dioxin-2,7(1H,6H)-dione. The crystals of C12H12O8,2(CH3)2SO are monoclinic, P21/n, a 7.859(5), b 9.774(7), c 13.14(1) &#506;, &#946; 93.08(6)&#176;, Z 2, with each molecule of the dione centred on a crystallographic centre of symmetry. The solvent molecules are disordered. The structure was refined by least squares to a residual of 0.046 for 1361 'observed' reflections. 
ER  -

