
TY  - JOUR
A1  - Dickinson, RG 
A1  - Jacobsen, NW 
A1  - Pitman, IH 
T1  - The hydrazinolysis of heterocyclic compounds. V. Reactions of 1-Amino-4,6-dimethylpyrimidin-2(1H)-one hydrazone in water
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 9
SP  - 2023
EP  - 2030
KW  - 
UR  - https://doi.org/10.1071/CH9782023 
N2  - The cation of 1-amino-4,6-dimethylpyrimidin-2(1H)-one hydrazone (1) is stable in aqueous solutions. By contrast the neutral molecule species decomposes to yield 3,5-dimethylpyrazole (3) and 1-amino-4,6- dimethylpyrimidin-2(1H)-one (6) as major products, and 1,2,4-triazole-3,4,5-triamine (7) and other unidentified compounds as minor products. Covalent hydration and substituent effects in the cation species of (1) are discussed in seeking an explanation for anomalous ultraviolet spectra. Hydrogen deuterium exchange in methyl substituents is reported. 
ER  -

