
TY  - JOUR
A1  - Bishop, R 
T1  - An N.M.R. investigation of the metal-ligand bonding in some transition metal complexes of Bicyclo[3,3,1]nona-2,6-diene
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 7
SP  - 1485
EP  - 1492
KW  - 
UR  - https://doi.org/10.1071/CH9781485 
N2  - The structure of the bicyclo[3,3,1]nona-2,6-diene complexes with formulae (diene)PdCl2, (diene)PtCl2, and [(diene)RhCl]2 has been shown, by use of 1H and 13C N.M.R. spectroscopy and deuterium labelling, to involve two equivalent metal-olefin bonds preferentially bonded to carbon atoms 2 and 6. Two crystalline forms (&#945;, &#946;) of the palladium complex were obtained. These were completely inter-convertible in either direction from solution, with the a-form being converted into the P-form (with concurrent halogen exchange) under i.r. KBr disc conditions. 
ER  -

