
TY  - JOUR
A1  - Figgis, BN 
A1  - Skelton, BW 
A1  - White, AH 
T1  - Crystal structures of the simple monoclinic and orthorhombic polytypes of tripotassium hexacyanoferrate(III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 6
SP  - 1195
EP  - 1199
KW  - 
UR  - https://doi.org/10.1071/CH9781195 
N2  - The room-temperature (295 K) crystal structures of potassium ferricyanide, K3[Fe(CN)6], have been determined for the simplest monoclinic (a reinvestigation) and orthorhombic polytypes by single- crystal X-ray diffraction. The monoclinic form is P21/c, a 7.047(3), b 10.400(3), c 8.384(3) &#506;, &#946; 107.29(3)&#176;, Z 2. The iron atoms lie on special positions with symmetry 1. In the orthorhombic form, Pnca, a 13.422(6), b 10.396(4), 8.381(4) &#506;, Z4, the iron atoms now lie on special positions with symmetry 2 (parallel to c). Residuals are 0.036 and 0.048 for 1232 and 855 'observed' reflections respectively. 
ER  -

