
TY  - JOUR
A1  - Bendall, MR 
A1  - Doddrell, DM 
T1  - Proton-deuterium isotope shifts in <sup>59</sup>Co N.M.R.
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 5
SP  - 1141
EP  - 1143
KW  - 
UR  - https://doi.org/10.1071/CH9781141 
N2  - An isotope shift of 5 ppm per deuterium atom has been observed for the 59Co resonance of tris(ethylenediamine)cobalt(III) chloride ([Co(en)3]Cl3) and hexaamminecobalt(III) chloride([Co(NH3)6]Cl3) after exchange of hydrogen for deuterium. The upfield direction of the shift can be readily understood as changes in the ligand-field strength causing changes in the nuclear paramagnetic screening. 
ER  -

