
TY  - JOUR
A1  - Jackson, WR 
A1  - Strauss, JU 
T1  - The stereochemistry of organometallic compounds. XVII. Reactions of &#960;-allylpalladium compounds with acetylacetone
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 5
SP  - 1073
EP  - 1079
KW  - 
UR  - https://doi.org/10.1071/CH9781073 
N2  - Reactions of &#960;-allylpalladium compounds with sodium acetylacetonate, sodium malononitrile, and sodium ethylacetoacetate in dimethyl sulfoxide solution give diallyl substitution products. Reaction of the acetylacetonate complexes with carbon monoxide in benzene give mono- allyl substitution products. Application of these reactions to the &#960;- allyl complexes from 1-acetyl-4-t-butylcyclohex-1-ene and from 3-oxo 4- ene steroids in an attempt to examine the stereochemistry of ligand transfer gave no substitution products. 
ER  -

