
%0 Journal Article
%A Jackson, WR 
%A Strauss, JU 
%T The stereochemistry of organometallic compounds. XVII. Reactions of &#960;-allylpalladium compounds with acetylacetone
%J Australian Journal of Chemistry
%D 1978/05/01
%V 31
%N 5
%P 1073-1079
%K 
%R https://doi.org/10.1071/CH9781073
%U https://www.publish.csiro.au/paper/CH9781073 
%X Reactions of &#960;-allylpalladium compounds with sodium acetylacetonate, sodium malononitrile, and sodium ethylacetoacetate in dimethyl sulfoxide solution give diallyl substitution products. Reaction of the acetylacetonate complexes with carbon monoxide in benzene give mono- allyl substitution products. Application of these reactions to the &#960;- allyl complexes from 1-acetyl-4-t-butylcyclohex-1-ene and from 3-oxo 4- ene steroids in an attempt to examine the stereochemistry of ligand transfer gave no substitution products. 
