
TY  - JOUR
A1  - Mitra, S 
A1  - Raston, CL 
A1  - White, AH 
T1  - Crystal structure of Tris(pyrrolidine-1-carbodithioato)iron(III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 3
SP  - 547
EP  - 553
KW  - 
UR  - https://doi.org/10.1071/CH9780547 
N2  - The crystal structure of the title compound, [Fe{CS2N(CH2)4}3] (a new phase prepared from chloro-form/toluene solutions), has been determined by single-crystal X-ray diffraction at 295 K and refined to a residual of 0.059 for 5651 'observed' reflections. Crystals are monoclinic, P21/a, a 18.033(6), b 9.398(2), c 13.176(6) &#506;, &#946; 100.80(3)&#176;, Z 4. The compound is a purely high-spin derivative, the iron atom being in the usual pseudo-D3 environment with <Fe-S> very long (2.456 &#506;). 
ER  -

