
%0 Journal Article
%A Salah, OMA 
%A Bruce, MI 
%T Chemistry of the Group 1B metals. X. Reactions between silver arylacetylides and some rhodium(I) and iridium(I) complexes
%J Australian Journal of Chemistry
%D 1977/12/01
%V 30
%N 12
%P 2639-2646
%K 
%R https://doi.org/10.1071/CH9772639
%U https://www.publish.csiro.au/paper/CH9772639 
%X Reactions between AgC2Ar (Ar = Ph or C6F5) and RhCl(PPh3)3 or IrCl(CO)(PPh3)2 have given hexanuclear heteroatom cluster compounds M2Ag4(C2Ar)8(PPh3)2 (M = Rh or Ir), and the zwitterionic complexes {[Ag(PPh3)]+ [M(C2C6F5)4(PPh3)2]-} and {[Ag(PPh3)]2+ [Rh(C2C6F5)5(PPh3)]  2-}.The structures of these complexes are described and discussed, together with possible reactions by which they may be formed. 
