
TY  - JOUR
A1  - Harris, RLN 
A1  - Huppatz, JL 
A1  - Phillips, JN 
T1  - The reaction of &#946;-N,N-Dialkylaminocrotonates with phosphorus oxychloride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1977
VL  - 30
IS  - 10
SP  - 2213
EP  - 2223
KW  - 
UR  - https://doi.org/10.1071/CH9772213 
N2  - &#946;-Dialkylaminocrotonates self-condense in excess phosphorus oxychloride at room temperature to give N,N-dialkylanthranilates in high yield. When stoichiometric amounts of phosphorus oxychloride are used and the reaction is carried out in benzene at 80°, significant amounts of phenolic by-products are also formed, which, in the case of &#946;- morpholinocrotonates, become the major products. These compounds have been subjected to a number of transformations which establish their structure and at the same time provide methods of synthesis for N,N-dialkylaniline derivatives which are otherwise difficult to obtain. 
ER  -

