
TY  - JOUR
A1  - Hall, SR 
A1  - Raston, CL 
A1  - White, AH 
T1  - Crystal structure of Hydroxyimino(N,N'-dimethyl)malonamide
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1977
VL  - 30
IS  - 9
SP  - 1929
EP  - 1936
KW  - 
UR  - https://doi.org/10.1071/CH9771929 
N2  - The crystal structure of the title compound, namely hydroxyimino(N,N?- dimethyl)malonamide (MeNHCOC(=NOH)CONHMe), has been determined by single-crystal X-ray diffraction with diffractometer data at 295 K. The structure was solved by direct methods and refined by least squares to a residual of 0.055 for 1477 observed reflections.     Crystal data: monoclinic, P21/n, a 15.508(3), b 10.544(2), c 9.377(1) &#506;, &#946; 103.15(2)°, Z 8.     The two crystallographically independent molecules exhibit little conjugation throughout the C-C-C skeleton (<C-C> 1.50 &#506;), the molecule being non-planar. <C=O> is 1.234, <N-CH3> 1.443, <OC-N> 1.323, <C-NO> 1.278 and (N-O) 1.375 &#506;. The geometry is compared with those observed for several related derivatives. 
ER  -

