
%0 Journal Article
%A Jackson, WR 
%A Strauss, JU 
%T The stereochemistry of organometallic compounds. XV. Reactions of the allylpalladium complexes of &#945;,&#946;-unsaturated ketones and esters with nucleophiles
%J Australian Journal of Chemistry
%D 1977/03/01
%V 30
%N 3
%P 553-562
%K 
%R https://doi.org/10.1071/CH9770553
%U https://www.publish.csiro.au/paper/CH9770553 
%X Reactions of &#960;-allylpalladium complexes of &#945;,&#946;-unsaturated ketones and esters with nucleophiles occur regioselectively at the &#947;-carbon atom to give high yields of &#947;-functionalized products. The E/Z-stereochemistry of the products is discussed in relation to the syn/anti- stereochemistry of the &#960;-allylpalladium compounds and the reactivity of the latter compounds is discussed in terms of their 1H and 13C N.M.R. spectra. 
