
TY  - JOUR
A1  - Pearson, AJ 
T1  - Alkylations of Tricarbonylcyclohexadienyliron Salts with Mixed Alkylcuprate Reagents
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1977
VL  - 30
IS  - 2
SP  - 345
EP  - 350
KW  - 
UR  - https://doi.org/10.1071/CH9770345 
N2  - A study of the reaction between mixed alkylcuprate reagents [Li(R1R2Cu)] with tricarbonylcyclohexadienylironsalts (1) has shown that, when R2 = SPh, alkylation of (1) may be achieved in moderate to good yields for R1 = Pri, Bu and But. Only minor yields are obtained for R1 = Me and CH2=CH, the main reaction being thiophenoxylation, but for these substituents alkylation is achieved with the dialkylcuprate. The regioselectivity of the reaction has been studied for a number of cuprate reagents. 
ER  -

