
TY  - JOUR
A1  - Dickson, RS 
A1  - Johnson, SH 
T1  - Reactions of Hex-3-yne with Dicarbonyl(&#951;-cyclopentadienyl)-cobalt and -rhodium
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 10
SP  - 2189
EP  - 2199
KW  - 
UR  - https://doi.org/10.1071/CH9762189 
N2  - The reaction of hex-3-yne with (&#951;-C5H5)Co(C0)2 gives the p-benzoquinone complex (&#951;-C5H5)Co-[(EtC2Et)2(C0)2] and the cyclopentadienone complex (q-C5H5)Co[(EtC2Et)2CO]. The corresponding reaction with (q-C2H2)Rh(CO)2 gives the cyclopentadienone complex (&#951;-C5H5)Rh[(EtC2Et)2C0] and a binuclear 4,6-diethylnonadien-5-one complex, (&#951;-C5H5)2Rh2(EtC2Et)2Co. The 1H N.M.R. spectra of all complexes have been analysed, in some instances with the aid of partial decoupling experiments. An analysis of the 13C N.M.R. spectra of the two cyclopentadienone complexes is also given. 
ER  -

