
TY  - JOUR
A1  - Colton, R 
A1  - McCormick, MJ 
T1  - Carbonyl halides of the Group VII transition metals. V. Derivatives of manganese halocarbonyls with Bis(diphenylarsino)methane
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 8
SP  - 1657
EP  - 1664
KW  - 
UR  - https://doi.org/10.1071/CH9761657 
N2  - The reactions between Mn(CO)5X(X = Cl, Br) and bis(diphenylarsino) methane, dam, have been studied. The most surprising feature of the system is the lack of complexes of the type [Mn(CO)3(dam)X]. Binuclear complexes [Mn2(CO)6(dam)X2] dominate the system and these show unusual disproportionation to Mn0 and Mn11. The reactions with the corresponding ditertiary phosphine, dpm, are much simpler and no binuclear complexes were observed. Infrared and N.M.R. studies have helped to elucidate the structures of the compounds prepared. 
ER  -

