
TY  - JOUR
A1  - Canty, AJ 
A1  - Marker, A 
T1  - Methylmercury(II) derivatives of Pyridine-2(1H)-thione
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 6
SP  - 1383
EP  - 1387
KW  - 
UR  - https://doi.org/10.1071/CH9761383 
N2  - Methylmercuric nitrate reacts with pyridine-2(lH)-thione (C5H5NS) in acetone to give methyl-(pyridine-2(1H)-thione)mercury(11) nitrate, [MeHg(C5H5NS)] NO3. This complex reacts with sodium bicarbonate in acetone to give methyl(pyridine-2-thiolato)mercury(11), MeHg(C5H4NS).Infrared, Raman, and nuclear magnetic resonance spectra indicate that MeHgH is bonded to sulphur in both complexes, and that protonation of nitrogen occurs on reaction of MeHg(CsH,NS) with nitric acid to give [MeHg(C5H5NS)] NO3. 
ER  -

