
%0 Journal Article
%A Hoskins, BF 
%A Martin, RL 
%A Rohde, NM 
%T Mossbauer spectrum, molecular and crystal structure of tin(II) diethyldithiocarbamate
%J Australian Journal of Chemistry
%D 1976/01/01
%V 29
%N 1
%P 213-217
%K 
%R https://doi.org/10.1071/CH9760213
%U https://www.publish.csiro.au/paper/CH9760213 
%X The syntheses and Mossbauer spectra of four sulphur-chelated compounds of tin(11) are reported. A single-crystal X-ray structure determination of Sn(dedtc)2 has established that the molecule possesses a strongly distorted trigonal bipyramidal configuration with a sterically active lone pair of electrons occupying an equatorial coordination position. While the Mossbauer quadrupole splitting for tin(11) compounds, in general, is consistent with a sterically active pair of electrons, its magnitude appears to be more sensitive to the nature of the ligand rather than the tin stereochemistry. 
