
TY  - JOUR
A1  - Anthony, RG 
A1  - Bloom, H 
T1  - Vapour pressures and activities in the reciprocal fused salt systems ZnCl<sub>2</sub> + Na<sub>2</sub>SO<sub>4</sub> and ZnSO<sub>4</sub> + NaCl
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 12
SP  - 2587
EP  - 2592
KW  - 
UR  - https://doi.org/10.1071/CH9752587 
N2  - Zinc chloride vapour pressures, activities and partial molar energies have been determined in the reciprocal fused salt system: Zn,Na/Cl,SO4 over the range 770-900 K. The transpiration vapour pressure of pure ZnCl2 was first redetermined for the range 720-900 K and found to follow the equation (in which P° is in mmHg):                  Log P°ZnCl2 = (-8247±17)/T-5.033 log T + 26.213 ± 0.006  Activities of ZnC1, in the reciprocal system differed greatly from ideality, the degree of departure varying with both composition and temperature. In general, at relatively high ZnCl, concentrations, observed activities were greater than ideal and ZnCl2 partial molar enthalpies were positive; this behaviour is believed to be largely caused by the effect of partial covalent bonding in pure ZnCl2. At low ZnCl2 concentrations, activities were much less than ideal and ZnCl2 partial molar enthalpies were negative; this other effect is believed to be caused by the formation of complex ions within this system. 
ER  -

