
TY  - JOUR
A1  - Fawcett, WR 
A1  - Krygowski, TM 
T1  - A complementary Lewis acid-base description of solvent effects. II. Dipole-dipole interactions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 10
SP  - 2115
EP  - 2124
KW  - 
UR  - https://doi.org/10.1071/CH9752115 
N2  - A previously described empirical model for solvent effects is applied to kinetic, thermodynamic and spectroscopic data selected to reflect variation in solute-solvent interactions of a dipole-dipole character. The three parameter fit was found to describe the solvent effect successfully in 75% of the cases considered. The choice of basicity parameters for protic solvents is discussed, and the basicity scales of Gutmann, Kagiya, Koppel and Palm, and Arnett, are compared. It is concluded that an extension of the present model should take into consideration entropic effects associated with solute-solvent interactions. 
ER  -

