
TY  - JOUR
A1  - Dash, UN 
A1  - Nayak, B 
T1  - Behaviour of the silver-silver bromide and the silver-silver iodide electrodes in formamide at different temperatures
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 8
SP  - 1657
EP  - 1661
KW  - 
UR  - https://doi.org/10.1071/CH9751657 
N2  - From the e.m.f. measurements of the buffered cells of the type                         Pt, H2|HOAc(m1), KOAc(m2), KX(m3)|AgX-Ag   the standard potentials of the Ag-AgX electrodes have been determined, in formamide, at nine different temperatures in the range 5-45°. The standard potentials of the Ag-AgX electrodes obtained at 25° are in good agreement with those obtained from the study of the cells                      Ag-AgX|KX(m3), KOAc(m2), HOAc(m1), QH2-Q|Pt   at 25°, where X is Br or I. The cell                              Pt,H2|HBr(m)|AgBr-Ag  has been further studied in this solvent at 25° with a view to having an independent check on these buffered cells for the standard potential of the Ag-AgBr electrode. The standard thermodynamic quantities (&#916;G°, &#916;H°, and &#916;S°) for the corresponding cell reactions have been calculated from the e.m.f. data over the range, 5-45°. 
ER  -

