
TY  - JOUR
A1  - Dash, UN 
A1  - Nayak, B 
T1  - Studies on the application of the quinhydrone electrode in formamide. V. The ionization constants of chloro- and phenyl-substituted acetic acids from E.M.F. measurements at different temperatures and the effect of substituents on the strength of acetic acid in formamide
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 8
SP  - 1649
EP  - 1651
KW  - 
UR  - https://doi.org/10.1071/CH9751649 
N2  - From the study of the cell                      Ag-AgCl|KCl(m3), KA(m2), HA(m1), QH2-Q|Pt  (where HA stands for acid) the ionization constants of chloroacetic acid in formamide have been determined at 25, 30 and 35°, and those of phenylacetic acid at nine different temperatures in the range 5-45°. The cell                      Pt, H2|HA(m1), KA(m2), KCl(m3)|AgCl-Ag   has also been used to redetermine the ionization constants of chloroacetic acid in formamide in the range 5-45°; the ionization constants of chloroacetic are in good agreement with those of an independent study. The effect of substituents on the strength of acetic acid has been examined in formamide. 
ER  -

