
TY  - JOUR
A1  - Dack, MRJ 
T1  - Solvent structure. The use of internal pressure and cohesive energy density to examine contributions to solvent-solvent interactions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 8
SP  - 1643
EP  - 1648
KW  - 
UR  - https://doi.org/10.1071/CH9751643 
N2  - Internal pressures, (&#8706;U/&#8706;V)T, have been obtained at 25° for the solvents dimethyl sulphoxide, propylene carbonate, formamide, dimethylformamide, acetonitrile, methanol and hexamethyl-phosphoramide by measurement of the thermal pressure coefficients. Data in the literature suggest that values of the internal pressure and the cohesive energy density, (&#916;U/Vm), are similar for a non-polar solvent. The observed divergence of the two properties in the polar solvents under investigation is discussed in terms of the nature of the solvent-solvent interactions. 
ER  -

