
TY  - JOUR
A1  - Kepert, DL 
A1  - Trigwell, KR 
T1  - Eight-coordinate complexes of titanium and niobium tetrachlorides with 1,8- Bisdimethylarsinonaphthalene
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 6
SP  - 1245
EP  - 1248
KW  - 
UR  - https://doi.org/10.1071/CH9751245 
N2  - Titanium and niobium tetrachlorides form the eight-coordinate adducts [TiCl4(naars)2] and[NbCl4(naars)2] with 1,8-bisdimethylarsinonaphthalene. The visible spectrum of the latter compound shows that as a result of the small ?bite? of this bidentate ligand, the order of orbital energies is dxy < dxz, dyz < dx2-y2 < dz2. 
ER  -

