
%0 Journal Article
%A Hsieh, ATT 
%A Sheahan, RM 
%A West, BO 
%T Dioxouranium(VI) complexes with N-salicylsalicylaldimines and their Lewis base adducts
%J Australian Journal of Chemistry
%D 1975/04/01
%V 28
%N 4
%P 885-891
%K 
%R https://doi.org/10.1071/CH9750885
%U https://www.publish.csiro.au/paper/CH9750885 
%X New dioxouranium(VI) complexes with the dibasic terdentate Schiff bases, XC6H3(2-OH)CH=N-CH2C6H4(2?-OH) (X = H, 5-Cl or 3-MeO), have been synthesized and characterized as their 1 : 1 alcohol adducts. The labile alcohol molecules in these complexes are readily replaced by various oxygen or nitrogen donor ligands, affording six- or seven- coordinate complexes. Evidence is presented for the rather weak coordination of these Lewis bases to the uranium metal atom. The various possible conformations for these [6,6]-membered chelate complexes are also discussed. 
