
TY  - JOUR
A1  - Harcourt, RD 
T1  - One-electron bonds as intermolecular bonds for molecular complexes involving Mulliken n-electron donors and as-electron acceptors
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 4
SP  - 881
EP  - 884
KW  - 
UR  - https://doi.org/10.1071/CH9750881 
N2  - For 1 : 1 molecular complexes involving an n-type electron donor and an a&#963;-type electron acceptor, it is proved that the simplest Mulliken description, &#936;N &#8776; &#936;(D,A)+&#955;&#936;(D+-A-), is equivalent to using a one-electron bond as the intermolecular bond between the donor (D) and the acceptor (A). The theory is illustrated with reference to the Hassel compound Me3N...I2, and the charge-transfer aspects of hydrogen bonding for the water dimer. 
ER  -

