
%0 Journal Article
%A Collins, DJ 
%A Hetherington, JW 
%A Swan, JM 
%T Organophosphorus compounds. XV. Synthesis of 2-Ethoxy-1-methyl-1,2-azaphospholidine 2-oxide
%J Australian Journal of Chemistry
%D 1974/08/01
%V 27
%N 8
%P 1759-1765
%K 
%R https://doi.org/10.1071/CH9741759
%U https://www.publish.csiro.au/paper/CH9741759 
%X The reaction of diethyl 3-bromopropylphosphonate with phosphorus pentachloride in carbon tetrachloride gave ethyl 3-bromopropylphosphonochloridate, which upon reaction with anhydrous methylamine at -15º gave ethyl N-methyl-P-3-bromopropylphosphonamidate. Treatment of this phosphonamidate with sodium hydride in boiling xylene gave 2-ethoxy-1-methyl-l,2-azaphospholidine 2-oxide. Some other possible routes to this compound were investigated. 
