
TY  - JOUR
A1  - Mahadevappa, DS 
A1  - Naidu, HMK 
T1  - Kinetics and mechanism of oxidation of allyl alchohol by chloramine-T in hydrochloric acid medium
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 6
SP  - 1203
EP  - 1207
KW  - 
UR  - https://doi.org/10.1071/CH9741203 
N2  - The kinetics of oxidation of allyl alcohol by chloramine-T in presence of hydrochloric acid (0.04-0.13M ) has been studied at O°C. The reaction shows first-order dependence on chloramine-T and hydrogen ion concentration and is independent of the concentration of alcohol. The energy and entropy of activation of the reaction have been found to be 12.3 kcal mol-1 and -33.2 e.u. respectively.Ionic strength has very little influence on the rate of reaction. A mechanism in terms of a fast interaction between allyl alcohol and hypochlorous acid formed by the hydrolysis of N-chloro-p-toluenesulphonamide in a slow step is proposed. 
ER  -

