
TY  - JOUR
A1  - Engelhardt, LM 
A1  - Newman, PWG 
A1  - Raston, CL 
A1  - White, AH 
T1  - Crystal structure of Hexakis(hydroxylamine-N)nickel(II) sulphate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 3
SP  - 503
EP  - 507
KW  - 
UR  - https://doi.org/10.1071/CH9740503 
N2  - The crystal structure of the title compound, [Ni(NH20H)6] SO4, has been determined at 298 K by photographic methods; the structure was solved by the heavy atom method and refined by block diagonal least-squares procedures to a residual of 0.095 (1166 independent reflections). Crystal data: triclinic, PI, a 14.026(3), b 6.741(2), c 6.358(1) Å, &#945;-98.35(2), &#946; 79.57(1), &#947; 95.06(2)º, Z 2. In the two crystallographically independent centrosymmetric cations, the nickel atoms are octahedrally coordinated by the ligand nitrogen atoms, (Ni-N), 2.12 Å, <N-O), 1.44 Å. The Ni-N-O angles range from 110 to 117º. The sulphate geometry is normal and undistorted. 
ER  -

