
TY  - JOUR
A1  - Graddon, DP 
A1  - Nyein, TT 
T1  - Thermodynamics of metal-ligand bond formation. IX. Trimerization and base addition of Bis(2,6-dimethylheptane-3,5-dionato)nickel(II)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 2
SP  - 407
EP  - 411
KW  - 
UR  - https://doi.org/10.1071/CH9740407 
N2  - The equilibrium constant for trimerization of bis(2,6-dimethylheptane-3,5-dionato)nicke1(11) in benzene solution at 30ºC has been determined spectrophotometrically, K = 2 x 103 I2 mol-1; the heat of trimerization has been determined calorimetrically, &#916;H = -7 kJ (g-atom Ni)1. Thermo- dynamic data have also been obtained for the base addition reactions with pyridine leading to first Ni2L4(py) then NiL2(py)2. Results are compared with those previously obtained for other nickel(11) &#946;-diketone complexes. 
ER  -

