
TY  - JOUR
A1  - Lincoln, SF 
A1  - West, RJ 
T1  - A nitrogen-14 magnetic resonance study of the exchange of acetonitrile on cobalt(II) complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 1
SP  - 97
EP  - 103
KW  - 
UR  - https://doi.org/10.1071/CH9740097 
N2  - A 14N N.M.R. study of the exchange of acetonitrile on high-spin Co(triol)(MeCN)32+ (kex = (23 ± 2) x 104 s-1 at 298 K; &#916;H? = 40 ± 2 kJ mol-1; &#916;S? = -9.6 ± 6.2 J mol-1 K-1), high-spin Co(trenol)(MeCN)~2+ (kex &#8805; 2-x 106 s-l at 223 K), and low-spin Co(cyclam)(MeCN)n2+ (where it is considered that n = 1 or 2 and kex &#8805; 8 x 106 s-1 at 266 K) is reported, as are the magnetic moments and visible spectra of these complex ions. 
ER  -

