
TY  - JOUR
A1  - Buckley, PD 
A1  - Furness, AR 
A1  - Jolley, KW 
A1  - Pinder, DN 
T1  - c. Internal rotation of the nitroso group in p-substituted nitrosoanilines by the density matrix line-shape method
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 1
SP  - 21
EP  - 26
KW  - 
UR  - https://doi.org/10.1071/CH9740021C 
N2  - Density matrix theory has been applied to study the barrier to internal rotation about the Ar-NO bond in N,N-dimethyl-p-nitrosoaniline and N,N-diethyl-p-nitrosoaniline. Theoretical fits to experimental n.m.r. spectra have been obtained in the range - 30&#176;C to +40&#176;C. Activation parameters have been determined and compared with those obtained by more approximate methods. 
ER  -

